Rheology is the scientific study of deformation and flow of matter. Some important rheologic characteristics of matter are viscosity and newtonian / non-newtonian behaviour.
Dynamic viscosity η
Between two plates of similar type with an area A and a distance x is filled in a homogeneous fluid. This fluid can be devided in parallel layers of differential thickness. If one of the plates is moved parallelly to the other plate with constant velocity the fluid layer directly adjoining to the plate will be accelerated on this side but also decelerated by the next fluid layer. So every layer is accelerated by the adjoining faster layer and decelerated by the slower one next to it.
This leads to a velocity profile between the plates which is linear in simple, idealised cases. It can be observed, that the force F, thats needed to set the plate in motion, is proportional to plate area A, to plate velocity v and inverse proportional to plate distance x. Summarised: The constant is the dynamic viscosity η (unit: N s / m² = Pa s). The higher the viscosity is the higher is the expenditure of energy to get the substance in motion. The shear stress τ is the relation of force to surface: The velocity gradient dv/dx is the shear rate γ. This leads to:
Kinematic viskosity ν
If the dynamic viscosity η of a substance is set in relation with its density ρ the kinematic viskosity ν is gained. It must be considered that both dynamic viscosity and density are temperature-dependend.
If the viscosity of a substance is independent of the shear rate it is a newtonian fluid. The shear rate is linear dependent of the shear stress. Movement of fluid particles is described by the Navier-Stokes equation. Examples for newtonian fluids are water, air and some oils/gases.
Many fluids don't show a linear relation of shear rate and shear stress or need a minimum shear rate before they show fluid behaviour. Depending on the shown characteristic, fluids can be classified:
- Sheer thinning: With increasing shear rate the viscosity decreases. Changes of the inner structure of the fluid causes a decreasing inner friction. These changes only depend on the shear rate and are independent on the time.
- Dilatant: Also called "shear thickening". Opposite effect of shear thinning substances, the materials' viscosity increases with increasing shear rate. Structure changes causes higher interactions between fluid particles.
- Yield point: Some substances show elastic behaviour up to a specific shear rate, but are fluid-like up from this yield point (yield strength). If the fluid is Newtonian above the yield point its called Bingham fluid, if it is Non-Newtonian its called Casson fluid.
- Thixotropy: At constant shear rate a fluid shows a time-depending decreasing of viscosity, the longer the fluid is sheared the lower viscosity becomes. After the end of shearing viscosity gets back to its original value, no permanent change is observable.
- Rheopexy: Opposite effect to thixotropy. Rheopexic fluids show a time-depending increasing of viscosity at constant shear rate. The increased viscosity falls back to its original value after end of shearing.
The effects of changes in temperature on the viscosity of a substance is descibed by the Andrade equation: a,b = specific parameters and T = thermodynamic temperature in K By raising the fluids temperature its viscosity decreases vice versa by cooling a fluid its viscosity increases. It must be observed that the specific parameters of the Andrade euqation are only valid in limited range. In cases of wider temperature-ranges different sets of parameters has to be choosen.
A flow caused by the relative motion of two plates is called Couette flow. No pressure gradient is needed, the flow is induced only by the plate-fluid power transmission.
General measuring methods rotational viscosimeter:
If the outer cylinder (sample cup) is rotating and the inner cylinder is fix it is a Couette system. If the outer cylinder is fix and the inner cylinder is rotating it is called Searle system. By shearing the the fluid in the gap between the cylinders the propelled cylinder is decelerated depending on the viscosity of the fluid. This deceleration gives the measuring signal which can be evaluated.
The difference between these two systems is the behaviour of the fluid respectively of the occuring flow in the gap. With a rotating outer cylinder (Couette system) a velocity gradient between the fluid layers is induced. The fluid flows laminary inside the gap without any radial velocity component. If the inner cylinder is rotating (Searle system) a velocity gradient in opposite direction compared to a Couette system is forming at low rotational speeds. At higher rotational speeds the flow is decomposing and turbulences (vortices) perpenticulary to the axis of rotation occur. This is called Taylor vortex and is induced by centrifugal forces which influence the fluid to move from the inside to the outside part of the gap. The vortices change the measurement results and must be compensated.
(Link will open in new window)
- Very good site about rheology (german)